Q.1.
Pick out the wrong statement.
Q.2.
Heat evolved/absorbed during conversion of a substance from one allotropic form to another is termed as the heat of
Q.3.
When a system is in equilibrium for all possible processes, the differential or finite change of entropy is
Q.4.
For a spontaneous process, free energy
Q.5.
A large iceberg melts at the base, but not at the top, because of the reason that
Q.6.
Joule-Thomson co-efficient depends on the
Q.7.
In Joule-Thomson porous plug experiment, the
Q.8.
Entropy, which is a measure of the disorder of a system is
Q.9.
Chemical potential (an intensive property) of a substance is a force that drives the chemical system to equilibrium and is equal to its partial molar properties. The reatio of chemical potential to free energy of a pure substance at oconstant temperature and pressure is
Q.10.
One ton of refrigeration capacity is equivalent to the heat removal rate of
Q.11.
In jet refrigerators, the refrigerating fluid is practically always
Q.12.
High __________ is an undesirable property for a good refrigerant.
Q.13.
Joule-Thomson Co-efficient at any point on the inversion curve is
Q.14.
Internal energy of an ideal gas
Q.15.
In an ideal refrigeration cycle, the change in internal energy of the fluid is
Q.16.
In the reaction; N₂ + O₂ ⇋ 2NO, increasing the pressure will result in
Q.17.
Number of degrees of freedom for a three phase system in equilibrium comprising of three non-reacting chemical species is
Q.18.
In a reversible chemical reaction (where, Δx = number of moles of products-number of moles of reactants )
Q.19.
Gibbs-Duhem equation relates composition in liquid phase and the __________ at constant temperature & pressure.
Q.20.
For multicomponent multiple phases to be in equilibrium at the same pressure and temperature, the __________ of each component must be same in all phases.
Q.21.
What is the ratio of adiabatic compressibility to isothermal compressibility?
Q.22.
Which of the following non-flow reversible compression processes require maximum work?
Q.23.
What is the value of Joule-Thomson co-efficient for an ideal gas?
Q.24.
Which of the following equations is used for the prediction of activity co-efficient from experiments?
Q.25.
The molar excess Gibbs free energy, gE, for a binary liquid mixture at T and P is given by, (gE/RT) = A . x₁. x₂, where A is a constant. The corresponding equation for ln y₁, where y₁ is the activity co-efficient of component 1, is
Q.26.

The co-efficient of performance (COP) of a refrigerating system, which is its index of performance, is defined as the ratio of useful refrigeration to the net work. The units of __________ and COP are the same.

Q.27.

A refrigeration cycle is a reversed heat engine. Which of the following has the maximum value of the co-efficient of performance (COP) for a given refrigeration effect ?

Q.28.

Equilibrium constant decreases as the temperature

Q.29.

Which of the following is not an intensive property ?

Q.30.

"At the absolute zero temperature, the entropy of every perfectly crystalline substance becomes zero". This follows from the

Q.31.

In a working refrigerator, the value of COP is always

Q.32.

Out of the following refrigration cycles, which one has the minimum COP (Co-efficient of performance)?

Q.33.

During Joule-Thomson expansion of gases

Q.34.

The accentric factor of a materical, 'ω', is defined as ω = -log10(Prsat)Tr-1 = 0.where, Prsat = reduced vapor pressure, Tr = reduced temperature. The value of accentric factor is always

Q.35.

For a cyclic process, a fixed ratio between heat and work

Q.36.

The shape of T-S diagram for Carnot Cycle is a

Q.37.

"Dry ice" is

Q.38.

In jet refrigerators, the refrigerating fluid is practically always

Q.39.

Water on heating from 1 to 4°C

Q.40.

__________ increases with increase in pressure.

Q.41.

All gases during throttling process at atmospheric temperature and pressure show a cooling effect except

Q.42.

Measurement of thermodynamic property of temperature is facilitated by __________ law of thermodynamics.

Q.43.

Degress of freedom at triple point will be

Q.44.

Which of the following is not a common refrigerant ?

Q.45.

For an isothermal process, the internal energy of a gas

Q.46.

Which of the following non-flow reversible compression processes require maximum work ?

Q.47.

Pick out the correct statement.

Q.48.

A refrigerator may be termed as a

Q.49.

Compressibility factor for almost all the gases are approximately same at the same

Q.50.

The theoretical minimum work required to separate one mole of a liquid mixture at 1 atm, containingmole % each of n- heptane and n- octane into pure compounds each at 1 atm is