Q.1.

"Law of corresponding states" says that

Q.2.

The most important application of distribution law is in

Q.3.

Pick out the correct statement.

Q.4.

In the equation, PVn = constant, if the value of n =then it represents a reversible __________ process.

Q.5.

Pick out the correct statement.

Q.6.

For a stable phase at constant pressure and temperature, the fugacity of each component in a binary system __________ as its mole fraction increases.

Q.7.

Pick out the wrong statement.

Q.8.

Keeping the pressure constant, to double the volume of a given mass of an ideal gas at 27°C, the temperature should be raised to __________ °C.

Q.9.

Air-refrigeration cycle

Q.10.

The first law of thermodynamics is a statement of conservation of

Q.11.

"When a system in equilibrium is subjected to a change in temperature, pressure or concentration, the equilibrium is displaced in a direction which tends to undo the effect of the change." This is called the

Q.12.

Pick out the correct statement.

Q.13.

Pick out the wrong statement.

Q.14.

"When a system in equilibrium is subjected to a change in temperature, pressure or concentration, the equilibrium is displaced in a direction which tends to undo the effect of the change." This is called the

Q.15.

The first law of thermodynamics is a statement of conservation of

Q.16.

Efficiency of a heat engine working on Carnot cycle between two temperature levels depends upon the

Q.17.

In vapour compression refrigeration system, if the evaporator temperature and the condenser temperatures are -13°C and 37°C respetively, the Carnot COP will be

Q.18.

Specific __________ does not change during a phase change (e.g. sublimation, melting, vaporisation etc.).

Q.19.

Sound waves propagation in air exemplifies an __________ process.

Q.20.

In Joule-Thomson porous plug experiment, the

Q.21.

Gibbs free energy of mixing at constant pressure and temperature is always

Q.22.

Heat of formation of an element in its standard state is

Q.23.

For equilibrium process (i.e. reversible) in an isolated system

Q.24.

The partial molar enthalpy of a component in an ideal binary gas mixture of composition Z, at a temperature T and pressure P, is a function only of

Q.25.

When liquid and vapour phase of multi-component system are in equilibrium (at a given temperature and pressure), then chemical potential of each component is

Q.26.

4 kg moles of an ideal gas expands in vacuum spontaneously. The work done is

Q.27.

Boiling of liquid is accompanied with increase in the

Q.28.

Gibbs phase rule finds application, when heat transfer occurs by

Q.29.

A/an __________ system is exemplified by a vessel containing a volatile liquid in contact with its vapor.

Q.30.

The expression for entropy change given by, ΔS = - nR ln (P2/P1), holds good for

Q.31.

Change of heat content when one mole of compound is burnt in oxygen at constant pressure is called the

Q.32.

The compressibility factor for an ideal gas isIts value for any other real gas is

Q.33.

For an exothremic reaction

Q.34.

With increase in reduced temperature, the fugacity co-efficient of a gas at constant reduced pressure

Q.35.

COP of a refrigerator drawing 1 kW of power per ton of refrigeration is about

Q.36.

Compressibility factor (i.e., the ratio of actual volume of gas to the volume predicted by ideal gas law) for all gases are

Q.37.

Change of state namely evaportation condensation, freezing and melting is an __________ process.

Q.38.

In a P-V diagram (for an ideal gas), an isothermal curve will coincide withan adiabatic curve (through a point), when

Q.39.

With increase in temperature, the internal energy of a substance

Q.40.

It is desired to bring about a certain change in the state of a system by performing work on the system under adiabatic conditions.

Q.41.

Clausius - Clayperon equation is applicable to __________ equilibrium processes.

Q.42.

The intensive properties are

Q.43.

A Carnot cycle consists of the following steps :

Q.44.

If two gases have same reduced temperature and reduced pressure, then they will have the same

Q.45.

Which of the following is an extensive property of a system ?

Q.46.

Pick out the wrong statement.

Q.47.

Gibbs-Duhem equation

Q.48.

For an ideal gas, the enthalpy

Q.49.

Entropy change for an irreversible isolated system is

Q.50.

The Joule-Thomson co-efficient is defined as (∂T/∂P)H. Its value at the inversion point is