'Unreacted core model' represents the reaction involving
In chamber process of sulphuric acid manufacture in industry, the gas phase oxidation of SO2 to SO3 is accomplished by a __________ reaction.
For the irreversible elementary reactions in parallel viz
, the rate of disappearance of 'X' is equal to
For a reaction of the type,
, the rate of reaction (- rx) is given by
A chemical reaction occurs when the energy of the reacting molecules is __________ the activation energy of the reaction.
If the rate of a chemical reaction becomes slower at a given temperature, then the
B.E.T. method can be used to determine the __________ of a porous catalyst.
The conversion XA and residence time data are collected for zero order liquid phase reaction in a stirred tank reactor. Which of the following will be a straight line ?
Exposure of a photographic plate to produce a latent image is an example of __________ reaction.
For a series of reactions
having k1 << k2, the reaction system can be approximated as




Given,
3H2 + CO = CH4 + H2O, KP = 101.84 and,
4H2 + CO2 = CH4 + 2H2O, KP = 101.17
the KP for the reaction CO + H2O = CO2 + H2 is
Space velocity
For identical flow rate, feed composition and for elementary first order reactions, 'N' equal sized mixed reactors in series with a total volume 'V' gives the same conversion as a single plug flow reactor of volume 'V' for constant density systems. This is true, when the value of 'N' is
Helium-mercury method is used for the measurement of the __________ of the catalyst.
What is the order of a chemical reaction whose rate is deter-mined by the variation of one concentration term only ?
The rate of the reaction, X
Y, quadruples when the concentration of 'X' is doubled. The rate expression for the reaction is, r = K Cxn, the value of 'n' in this case will be
In case of the irreversible unimolecular type, first order reaction, the fractional conversion at any time for constant volume system as compared to variable volume system is
The reaction in which the rate equation corresponds to a stoichiometric equation, is called a/an __________ reaction.
Photochemical reaction rate does not depend significantly on temperature, because
A reaction which is catalysed by a base is catalysed by all substances which have a tendency to
A reaction which is catalysed by a base is catalysed by all substances which have a tendency to
Pick out the wrong statement.
Which of the following resistances is not involved in a gas phase catalytic (gas-solid) reaction ?
Pick out the wrong statement.
The optimum performance for reactors operating in parallel is obtained when the feed stream is distributed in such a way, that the
According to the 'law of mass action', the rate of reaction is directly proportional to the
Pick out the wrong statement.
For a homogeneous reaction of nth order, the dimension of the rate constant is given by
If the time required to change the concentration of reactant to half its original value is independent of the initial concentration, the order of reaction is
There is no correspondence between stoichiometry and the rate equation in case of a/an __________ reaction.
A catalyst is said to be a negative catalyst, ifit
In a chemical reaction, __________ are conserved.
The reaction A
B is conducted in an isothermal batch reactor. If the conversion of A increases linearly with holding time, then the order of the reaction is
In a chemical reaction, __________ are conserved.
Which of the following is used for calcination of limestone and dolomite in industrial practice ?
For the non catalytic reaction of particles with surrounding fluid, the same needed to achive the same fractional conversion for particles of different unchanging sizes is proportional to the particle diameter, when the __________ is the controlling resistance.
For an ideal gas mixture undergoing a reversible gaseous phase chemical reaction, the equilibrium constant
The fractional volume change between no conversion and complete conversion, for the isothermal gas phase reaction, 2A
R, is
A photochemical reaction is
A photochemical reaction is
Which of the following is used for calcination of limestone and dolomite in industrial practice ?
Pure ethanol vapor is fed to a reactor packed with alumina catalyst, at the rate ofkmole / hr. The reactor products comprise: ethylene :kmole / hr, water vapour: 97.5 k mole / hr and diethyl ether :2.5 kmole/hr. The reactions occuring can be represented by:
C2H5OH
C2H4 + H2O
2C2H5OH
C2H5 - O - C2H5 + H2O
The percent conversion of ethanol in the reactor is
Pure ethanol vapor is fed to a reactor packed with alumina catalyst, at the rate ofkmole / hr. The reactor products comprise: ethylene :kmole / hr, water vapour: 97.5 k mole / hr and diethyl ether :2.5 kmole/hr. The reactions occuring can be represented by:
C2H5OH
C2H4 + H2O
2C2H5OH
C2H5 - O - C2H5 + H2O
The percent conversion of ethanol in the reactor is
A photochemical reaction is