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NEET Chemistry MCQ
Alcohols, Phenols And Ethers Mcq Neet Chemistry
Quiz 13
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Q.1
The organic compound present in tincture of iodine is .... ....
0%
a) CS2
0%
b) CCl4
0%
c) alcohol
0%
d) acetone
Explanation
Answer : (c)
Q.2
In esterification of an acid, the other reagent is ... .....
0%
a) Water
0%
b) alcohol
0%
c) aldehyde
0%
d) amine
Explanation
Answer : (b)
Q.3
For the preparation tert- butylmethylether by Williamson's method the correct choice of reagents is ... ...
0%
a) methoxide and tert-butylbromide
0%
b) methanol and 2-bromobutane
0%
c) 2-butanol and methylbromide
0%
d) tert-butoxide and methylbromide
Explanation
tertiary halides do not undergo Williamson's synthesis. To get tert-alkylether, tert-alkoxide and alkyl halides should be used Answer : (d)
Q.4
Which of the property give below is not associated with glycerol? ....
0%
a) Formation of allyl iodide with PI3
0%
b) Formation of tartronic acid on oxidation
0%
c) Formation of tartronic acid on oxidation
0%
d) Formation of water and CO2 on reduction
Explanation
Glycerol is not reduced because of extensive H-bonding Answer : (d)
Q.5
Power alcohol is a mixture of petrol and alcohol in the ratio of .... ...
0%
a) 1:2
0%
b) 2:1
0%
c) 1:4
0%
d) 4:1
Explanation
Answer : (d)
Q.6
Primary and secondary alcohols on action of reduced copper give ... ....
0%
a) Only aldehydes
0%
b) Only ketones
0%
c) aldehydes and ketones respectively
0%
d) ketones and aldehyde respectively
Explanation
Tertiary alcohols gives alkene Answer : (c)
Q.7
When acetamide is treated with LiAlH4 .... .... is formed
0%
a) acetic acid
0%
b) methanol
0%
c) formic acid
0%
d) ethanol
Explanation
Answer : (d)
Q.8
Ethanol reacts with thionyl chloride to give ethyl chloride and .... ....
0%
a) S, SO2
0%
b) SO2, HCl
0%
c) SO3, HCl
0%
d) Cl2, SO3
Explanation
C2H5OH + SOCl2 → C2H5Cl + SO2 + HCl Answer : (b)
Q.9
Alcoholic fermentation of sugar gives 3% glycerol. The yield can be increased to 25% if fermentation is made in presence of ... ...
0%
a) Na2S
0%
b) Na2SO4
0%
c) Na3PO4
0%
d) none of these
Explanation
Answer : (a)
Q.10
For one mole of glycerol, how many mole of acetyl chloride are required for complete acetylation?
0%
a) One
0%
b) Two
0%
c) Three
0%
d) Four
Explanation
One mole of CH3COCl reacts at one -OH group replacing H by CH3CO group Glycerol contain three -OH group Answer : (c)
Q.11
The number of methoxy groups in a compound can be determined by treating it with .... ...
0%
a) Sodium carbonate
0%
b) acetic acid
0%
c) HI and AgNO3
0%
d) sodium hydroxide
Explanation
CH3OC2H5 + HI → CH3I + C2H5OH CH3I + AgNO3 → AgI + CH3 + CH3NO3 Answer : (c)
Q.12
Glycol condenses with ketones to give .... ....
0%
a) cyclic acid
0%
b) cyclic ketals
0%
c) acetaldehyde
0%
d) oxalic acid
Explanation
Answer : (b)
Q.13
The general molecular formula, which represents the homologous series of alkanols is .....
0%
a) CnH2n+1O
0%
b) CnH2n+2O
0%
c) CnH2nO2
0%
d) CnH2nO
Explanation
Answer : (b)
Q.14
on Q374) The principal organic product in the reaction is
0%
a)
0%
b)
0%
c)
0%
d)
Explanation
This is acid catalysed cleavage of cyclic ether where nucleophile attacks the more substitutes carbon Answer : (b)
Q.15
Sodium ethoxide is obtained by the reaction of ethyl alcohol with .... .....
0%
a) NaOH
0%
b) NaHCO3
0%
c) NaCl
0%
d) Na
Explanation
ROH + Na → RONa + ½ H2 Answer : (d)
Q.16
Decreasing order of boiling points of n-pentanol (A), n-pentane (B), 3-pentanol (C) and 2,2-dimethyl propanol (D) is .... ..
0%
a) A, B, C, D
0%
b) B, A, C, D
0%
c) A, D, C, B
0%
d) A, C, D, B
Explanation
Boiling point of alcohols are more than alkane; also more is the surface area, more in b.p. of alcohol Answer : (d)
Q.17
Which of the following is insoluble in alcohol?
0%
a) Soaps and varnishes
0%
b) Dyes and drugs
0%
c) Rubbers and plastics
0%
d) Resins and varnishes
Explanation
Answer : (c)
Q.18
han One Correct Answer Q378) The compound(s) which is/are used as anaesthetic is/are
0%
a) CHCl3
0%
b) ethyl alcohol
0%
c) ether
0%
d) carbon tetrachloride
Explanation
Answer : (a,c)
Q.19
Acrolein is obtained when glycerol is dehydrated with .... ...
0%
a) P2O5
0%
b) conc. H2SO4
0%
c) KHSO4
0%
d) all of these
Explanation
Answer : (d)
Q.20
Ethers are quite stable towards ... ....
0%
a) Oxidising agent
0%
b) Base
0%
c) Na Matel
0%
d) Reducing agent
Explanation
Answer : (a)
Q.21
Phenol does not react with ....
0%
a) Na2CO3
0%
b) NaOH
0%
c) NaHCO3
0%
d) KOH
Explanation
Phenol is weak acid Answer : (c)
Q.22
A mixture of alcohol and ether is called .... ....
0%
a) power alcohol
0%
b) natalite
0%
c) peroxide
0%
d) none of these
Explanation
It is a substitute of petrol Answer : (b)
Q.23
Diethyl ether may be regarded as anhydride of .... ...
0%
a) C2H5COOH
0%
b) C2H5COOC2H5
0%
c) C2H5OH
0%
d) C2H5CHO
Explanation
C2H5OH + C2H5OH → C2H5O C2H5OH + H2O Answer : (c)
Q.24
Glycerol on oxidation with dil.HNO3 gives
0%
a) tarronic acid
0%
b) glyceric acid
0%
c) mesoxalic acid
0%
d) oxalic acid
Explanation
Answer : (b)
Q.25
The characteristic group of secondary alcohol is .....
0%
a) - CH2OH
0%
b) - COOH
0%
c)
0%
d)
Explanation
Answer : (c)
Q.26
Formic acid is obtained when .... ....
0%
a) glycerol is heated with oxalic acid at 110°C
0%
b) calcium formate is heated with calcium acetate
0%
c) acetaldehyde is oxidized with K2Cr2O7 and conc. H2SO4
0%
d) (CH3COO)2Ca is heated with conc. H2SO4
Explanation
Answer : (a)
Q.27
Which one has highest boiling point>
0%
a) Butan-1-ol
0%
b) Butane
0%
c) Ethane
0%
d) hexane
Explanation
Because of H-bonding Butan-1-ol have highest boiling point Answer : (a)
Q.28
Acetic acid is obtained from ethyl alcohol by process of ... ..
0%
a) distillation
0%
b) reduction
0%
c) dehydration
0%
d) fermentation
Explanation
Acetyl bacilli convert ethyl alcohol to acetic acid Answer : (d)
Q.29
han One Correct Answer Q389) Which will give a yellow precipitate with iodine and alkali?
0%
a) 2-hydroxy propane
0%
b) Acetophenone
0%
c)Methanol
0%
d) Acetamide
Explanation
Answer : ( a, b)
Q.30
In the fermentation of sugar molasses, the percentage of ethanol formed is .... ....
0%
a) 10%
0%
b) 40%
0%
c) 70%
0%
d) 95%
Explanation
Answer : (a)
0 h : 0 m : 1 s
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