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Quiz 3
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Q.1
The protecting power of lyophilic colloidal sol is expressed in terms of …[ AIPMT 2012]
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a) coagulation value
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b) gold number
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c) critical micelle concentration
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d) oxidation number
Explanation
A protective colloid is a lyophilic colloid that when present in small quantities keeps lyophobic colloids from precipitating under the coagulating action of electrolytes. Gold number is defined as the minimum amount of protective colloid in milligrams .More is the gold number, less is the protective power of the lyophilic colloid since it means that the amount Answer: (b)
Q.2
Which is not a colloid?
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a) Egg white
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b) Chlorophyll
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c) Milk
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d) Ruby glass
Explanation
Answer: (b)
Q.3
Among the electrolytes Na2SO4, CaCl2., Al2(SO4)3 and NH4Cl, the most effective coagulating agent for Sb2S3 sol is … [ IIT 2009]
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a) Al2(SO4)3
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b) NH4Cl
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c) CaCl2.
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d) Na2SO4,
Explanation
Answer: (a)
Q.4
AlCl3 in Friedel-Craft reaction acts as
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a) oxidizing agent
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b) reducing agent
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c) acid catalyst
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d) none of these
Explanation
Answer: (c)
Q.5
A catalyst is a substance which …[ IIT 1984]
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a) changes the equilibrium conc. Of reaction
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b) supplied the energy of the reaction
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c) Increases equilibrium constant of reaction
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d) Shortens the time to reach equilibrium
Explanation
Answer: (d)
Q.6
If x is amount of adsorbate and m is amount of adsorbent, which of the following relations is not related to adsorption process? [ AIPMT 2001]
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a) x/m = f(T) at constant p
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b) p = f(T) at constant (x/m)
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c) x/m = p ×T
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d) x/m = f(p) at constant T
Explanation
Physical adsorption is an exothermic process, it occurs more readily at lower temperatures and decreases with increase in temperature (Le-Chatelier's Principle). The Freundlich adsorption isotherm is mathematically expressed as x/m = kp1/n Thus correct equation is x/m ∝ p/T. and not x/m = p×T Answer: (c)
Q.7
During dialysis
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a) only solvent molecules can diffuse
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b) Solvent molecules, ions and colloidal particles anc diffuse
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c) all kinds of particles can diffuse through the semipermeable membrane
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d) solvent molecules and ions can diffuse
Explanation
Answer: (d)
Q.8
Which acts as a promoter foor nickel in the hydrogenation of oils?
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a) Cu
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b) vanadium
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c) Pt
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d) Fe
Explanation
Answer: (a)
Q.9
Which is not correct regarding the adsorption of gas on surface of solid? [ AIPMT 2001]
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a) On increasing temperature adsorption increases continuously
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b) Enthalpy and entropy changes change is negative
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c) Adsorption is more for some specific substance
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d) Reversible
Explanation
Answer: (a)
Q.10
Which statement about enzymes is not correct?
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a) Enzymes are in colloidal state
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b) Enzymes are catalysts
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c) Enzymes can catalyse any reaction
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d) Urease is an enzyme
Explanation
Answer: (c)
Q.11
The protective power of lyophilic sol is
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a) Dependent on the size of colloidal particles
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b) expressed in terns of gold number
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c) expressed as x/m
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d) directly proportional to the magnitude of charge on it
Explanation
Answer: (c)
Q.12
Which of the following catalsy can be used in the contact process of sulphuric acid ..
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a) Pt
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b) Fe
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c) Cu
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d) Ni
Explanation
Answer: (a)
Q.13
Lyophilic sols are : [ IIT 2005]
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a) Not coagulated by adding electrolytes
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b) Irreversible sols
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c) They are prepared from inorganic compounds
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d) Self stabilizing
Explanation
Answer: (d)
Q.14
The Brownian motion is due to ... ...
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a) temperature fluctuation within the liquid phase
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b) attraction and repulsion between charges on the colloidal particles
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c) due to their collisions with other atoms or molecules
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d) concective current
Explanation
Answer: (c)
Q.15
The gold numbers of four protective colloids O, P, Q and R are 0.005, 0.01, 0.1 and 0.5 respectively. the decreasing order of their protective power is
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a) R, Q, P, Q
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b) O, P, Q, R
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c) P, Q, R, Q
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d) Q, R, O, P
Explanation
Answer: (b)
Q.16
The reactions in which catalyst and reactant have one phase are known as
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a) gaseous reaction
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b) heterogeneous catalytic reaction
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c) homogeneous catalytic reaction
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d) none of the above
Explanation
Answer: (c)
Q.17
Which of the following statements is incorrect regarding physisorptions? [ AIEEE 2009]
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a) It occurs because of van der Waals’ forces
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b) More easily liquefiable gases are adsorbed readily
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c) Enthalpy of adsorption ( ΔHadsorption) is low and positive
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d) Under high pressure it results into
Explanation
Answer: (c)
Q.18
Reason for the effect of catalyst on the rate of reaction reversible reaction is
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a) It increases the kinetic energy of reactant molecules
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b) It lowers the equilibrium conatsnt
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c) It decreases the rate of reverse reactioon
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d) It provides a new reaction pathway with lower activation energy
Explanation
Answer: (d)
Q.19
A catalyst … [ IIT 1983]
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a) Alters the reaction mechanism
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b) Increases the frequency of collisions of the reacting species
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c) Increases the average kinetic energy of the reactiong molecules
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d) Increases the activation energy
Explanation
Answer: (a)
Q.20
According to freundlich adsorption isotherm, which of the following is correct?
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a) x/m ∝ p1
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b) x/m ∝ p1/m
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c) x/m ∝ p0
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d) All the above are correct for different ranges of pressure
Explanation
Answer: (d)
Q.21
Which statement is correct?
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a) Physical adsorption is multi-layer, non-directional and non-specific
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b) Chemical adsorption is unilayer
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c) Chemical adsorption is more stronger than physical adsorption
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d) All of the above
Explanation
Answer: (d)
Q.22
Among the following surfactant molecules, the surfactant that forms micelles in aqueous solution at the lower CMC at ambient conduction is …[ IIIT 2008]
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a) CH3(CH2)11OS3- Na+
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b) CH3(CH2)15N+ (CH3)3 Br-
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c) CH3(CH2)11 M+ (CH3)3 Br-
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d) CH3(CH2)6COO3- Na+
Explanation
More is the hydrophobic character in surfactant molecule less is CMC in aqueous solution Answer: (b)
Q.23
Which statements are correct for physical adsorption?
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a) It is multilayer, non-directiional and non-specific
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b) Endothermic ΔH = +20 to +40 kJ/mol
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c) Exothermic with Δ H = -1000 kJ/mol
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d) It is irreversible process
Explanation
Answer: (a)
Q.24
Solvent loving colloids are
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a) lyophilic
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b) lyophilic colloid
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c) hydrophobic colloid
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d) none of these
Explanation
Answer: (b)
Q.25
On adding few drops of dil. HCl to freshly precipitated ferric hydroxide, a red coloured colloidal solution is obtained. This phenomenon is known as
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a) peptisation
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b) dialysis
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c) protective action
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d) dissolution
Explanation
Answer: (a)
Q.26
The size of the colloid particles is ...
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a) > suspension particles
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b) < suspension particles
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c) < true solution particles
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d) none of these
Explanation
Answer: (b)
Q.27
Chemisorption is ...
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a) multimolecular in nature
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b) reversible
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c) often highly specific and directional
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d) not very specific
Explanation
Answer: (c)
Q.28
The arsenious sulphide sol has negative charge. The maximum coagulation power for precipitating it is of … [ Roorkee 1990]
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a) 0.1 N Na3PO4
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b) 0.1 N Zn(NO3)2
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c) 0.1 N ZaSO4
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d) 0.1 N AlCl3
Explanation
Answer: (d)
Q.29
Enzymes are ....
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a) Substances made by chemists to activate washing powder
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b) very active vegetable catalysts
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c) catalysts found in organisms
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d) synthetic catalysts
Explanation
Answer: (c)
Q.30
The examples of aersol are
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a) air bubble
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b) pumice stone
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c) egg yolk
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d) cloud
Explanation
Answer: (d)
0 h : 0 m : 1 s
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